ESR evidence for the intermediacy of diazenium radicals in the photolysis of azoesters
✍ Scribed by Peter Stilbs; Göran Ahlgren; Björn Akermark
- Book ID
- 108384541
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 202 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
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## CIDNP-detactcd ESR spectra of short-hvcd radxal pairs in the photolysis of qunone (pbemzoquinon~ end duroquinone) have been sludied The infh~cnce of lhe saluraung rf-tield amplitude on the ESR spect.xa of radical pairs detected by lhis melhod hes been dcmonskucd and invatigatcd
## Abstract Various __N__‐nitrosamines were photolyzed in toluene solution in the temperature range −100°C to −30°C to yield dialkyl nitroxides. The nitrosamines studied were __N__‐nitrosodimethylamine, __N__‐nitrosodiethylamine, __N__‐nitrosodipropylamine, __N__‐nitrosodibutylamine and __N__‐nitro