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ESR evidence for a heterolytic C,O-bond cleavage in models of 4′-DNA radicals

✍ Scribed by Stefan Peukert; Rohit Batra; Bernd Giese

Book ID
104257039
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
166 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

Phatolysis of ketone 6b generates allyfic radical 9. The decisive step in this transformation is a heterolytic C,O-bond cleavage from radical 7b that generates radical cation 8 from raddtxd 7b. This ESR study models the anaerobic strand scission of4'-DNA rad/ca/s.

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