## Abstract Racemic 1‐ and 2‐naphthylmethoxyacetic acids (1NMA and 2NMA), the chiral anisotropic reagents used for absolute configuration determination of chiral secondary alcohols and primary amines, were conveniently resolved to enantiomers (>99% ee) by condensation with L‐phenylalaninol (2‐amino
✦ LIBER ✦
erythro -1-Naphthyl-1-(2-piperidyl)methanol: Synthesis, Resolution, NMR Relative Configuration, and VCD Absolute Configuration
✍ Scribed by Solladié-Cavallo, A.; Marsol, C.; Yaakoub, M.; Azyat, K.; Klein, A.; Roje, M.; Suteu, C.; Freedman, T. B.; Cao, X.; Nafie, L. A.
- Book ID
- 127170328
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 282 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Resolution of 1- and 2-naphthylmethoxyac
✍
Shoko Arita; Tetsuya Yabuuchi; Takenori Kusumi
📂
Article
📅
2003
🏛
John Wiley and Sons
🌐
English
⚖ 96 KB
Practical enantioresolution of alcohols
✍
Hiromi Taji; Yusuke Kasai; Akinori Sugio; Shunsuke Kuwahara; Masataka Watanabe;
📂
Article
📅
2001
🏛
John Wiley and Sons
🌐
English
⚖ 91 KB
👁 1 views
6-Chloro-2,3-dihydro-4H-1-benzopyran car
✍
Fulvio Loiodice; Antonio Longo; Pasquale Bianco; Vincenzo Tortorella
📂
Article
📅
1995
🏛
Elsevier Science
🌐
English
⚖ 624 KB
Optically active 2,2-dimethyl-1,3,4-tria
✍
Remir G. Kostyanovsky; Pavel E. Dormov; Peteris Trapencieris; Boriss Strumfs; Gu
📂
Article
📅
1999
🏛
Royal Society of Chemistry
🌐
English
⚖ 89 KB
ChemInform Abstract: Optically Active 2,
✍
Remir G. Kostyanovsky; Pavel E. Dormov; Peteris Trapencieris; Boriss Strumfs; Gu
📂
Article
📅
2010
🏛
John Wiley and Sons
⚖ 31 KB
👁 1 views
The racemic title bicycle (V) undergoes spontaneous resolution on crystallization from chloroform or acetone. The absolute configuration of the obtained enantiopure product (16-44% e.e.) is determined by comparison with (S)-(V) derived from (S)-Ser-OMe (I). Mutarotation due to partial conversion of
Enantioselective Synthesis and Absolute
✍
Zacchino, Susana A.; Badano, Hector
📂
Article
📅
1988
🏛
American Chemical Society
🌐
English
⚖ 302 KB