Errors in analyses of lanthanide-induced shifts. Cis- and Trans-pinocarveol
✍ Scribed by C.C Hinckley; W.C Brumley
- Book ID
- 103186751
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 794 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0022-2364
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The 13C chemical shifts of cis-and trans-benzylidenepropylamine and substituted benzylideneanilines were analysed after additons of Eu(fod),. The cisltrans ratio increases as the amount of lanthanide shift reagent increased. The cis isomers showed large lanthanide-induced shifts, whereas the trans i
## Abstract The use of Eu(fod)~3~ in the analysis of the ^1^H and ^13^C NMR spectra of __cis__ and __trans__‐fused β‐hydroxydecalones is described. The relative configuration of the substituents is discussed using the PMLIS algorithm to determine the lanthanide (Eu) ion position in the complex in a
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