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Equilibriums between triplet states of aromatic hydrocarbons

✍ Scribed by Kira, A.; Thomas, J. K.

Book ID
120370526
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
446 KB
Volume
78
Category
Article
ISSN
0022-3654

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The emission and transient absorption spectra of the intramolecular van der Waals dimer of 1,l '-di-a-naphthylmethane (a-DNM) trapped in a low temperature glassy matrix are compared with those of the intramolecular triplet excimer of the same species produced in fluid solution at room temperature.

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## Abstract The difference between the triplet‐triplet and singlet‐singlet absorption spectrum of naphthalene has been measured at 90Β°K using a newly developed computer controlled spectrograph. Good spectral resolution has been obtained and a strong band was found in the ultraviolet region. Recent