✦ LIBER ✦

Equilibrium rations of hydrogen and the critical loci of hydrogen-paraffin mixtures

✍ Scribed by J. M. Lenoir; H. G. Hipkin

Publisher: American Institute of Chemical Engineers
Year: 1957
Tongue: English
Weight: 398 KB
Volume: 3
Category: Article
ISSN: 0001-1541
DOI: 10.1002/aic.690030306

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✦ Synopsis

Abstract

This paper presentes a correlation to predict the equilibrium ratios of hydrogen in hydrocarbon mixtures by use of the parameters of pressure and convergence pressure. Also a procedure to predict convergence pressures of hydrogen‐containing mixtures was developed from a correlation of critical loci. With the predicted convergence pressure the measured values of hydrogen equilibrium ratios in binary hydrogen‐paraffin mixtures were predicted with a statistical deviation of 8.1% for 237 measurements. Including hydrogen‐olefin and multicomponent mixtures of hydrogen, paraffins, and olefins, the statistical deviation was found to be 11.3% for a total of 375 comparisons with measured values of hydrogen equilibrium ratios.

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