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Equilibrium of isobutylene and hydrogen chloride reaction with tert-butyl chloride over nickel films

✍ Scribed by J.S. Campbell; Chas. Kemball

Book ID
113172557
Publisher
Elsevier Science
Year
1964
Tongue
English
Weight
88 KB
Volume
3
Category
Article
ISSN
0021-9517

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✍ Ido P. Bleeker; Jan B. F. N. Engberts 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 345 KB

## Abstract tert‐Butylsulfinyl chloride (**1**) reacts smoothly with tert‐butyl hydroperoxide (**2**) in the presence of pyridine to afford a variety of products including pyridinium tert‐butylsulfonate, tert‐butyl tert‐butylthiolsulfonate, tert‐butanol and tert‐butylsulfonyl chloride. The mechanis