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Organic peroxides. XL. Reaction of sym- and unsym- phthaloyl chloride with tert-butyl hydroperoxide

✍ Scribed by Klein, Rainer J.; Milas, Nicholas A.


Book ID
127197871
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
484 KB
Volume
36
Category
Article
ISSN
0022-3263

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Reactions of tert-butylsulfinyl chloride
✍ Ido P. Bleeker; Jan B. F. N. Engberts 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 345 KB

## Abstract tert‐Butylsulfinyl chloride (**1**) reacts smoothly with tert‐butyl hydroperoxide (**2**) in the presence of pyridine to afford a variety of products including pyridinium tert‐butylsulfonate, tert‐butyl tert‐butylthiolsulfonate, tert‐butanol and tert‐butylsulfonyl chloride. The mechanis