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Equilibrium constants and rate constants for the transformations in aqueous solution of a spirocyclic hydroxyphosphorane

✍ Scribed by McClelland, Robert A.; Cramm, David A.; McGall, Glenn H.


Book ID
126460630
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
628 KB
Volume
108
Category
Article
ISSN
0002-7863

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Rate constants for Hydrogen abstraction
✍ L. V. Shastri; Robert E. Huie πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 392 KB πŸ‘ 2 views

Rate constants have been measured by pulse radiolysis for the reactions of the NO, radical with five cyclic ethers and a series of alcohols. Rate constants ranged from 3.5 x lo4 M-' 5 -l for deuterated methanol to 1.1 x lo7 M-' 5-l for tetrahydrofuran. The rate constants for the reactions of NO3 wit