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Equilibrium Characterization and Alkylation Kinetics of a Lithium Enolate−Lithium Bromide Mixed Aggregate in THF 1

✍ Scribed by Abu-Hasanayn, Faraj; Streitwieser, Andrew

Book ID
127051005
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
136 KB
Volume
118
Category
Article
ISSN
0002-7863

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Enantioselective alkylation of lactams a
Enantioselective alkylation of lactams and lactones via lithium enolate formation using a chiral tetradentate lithium amide in the presence of lithium bromide
✍ Jun-ichi Matsuo; Shu Kobayashi; Kenji Koga 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 210 KB

Enantioselective alkylation of lactams and lactones can be realized up to 98% ee by deprotonation with a chiral tetradentate lithium amide (4b) in the presence of lithium bromide, and subsequent alkylation with active alkylating agents in non-chelating solvents.