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Equilibrium between H3O+ and NH4+ ions in the flame ionization detector

โœ Scribed by T. McAllister

Book ID
107771878
Publisher
Elsevier Science
Year
1983
Weight
257 KB
Volume
47
Category
Article
ISSN
0020-7381

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Stability, association, and dissociation
Stability, association, and dissociation in the cluster ions H3S+.+-..nH2S, H3O+.+-..nH2O, and H3S+.H2O
โœ Meot-Ner, M.; Field, F. H. ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 703 KB

Cluster ion stabilities were measured by pulsed, high-pressure mass spectrometry. Enthalpies for the reactions H,O+.( n -1)HzO + HzO + M -H,O+.nH20 + M were measured as -33.0, -21.0, and -16.0 kcal/mol for n = I , 2, and 3, respectively, in good agreement w i t h values obtained by Kebarle and co-wo