An cquatlon of state, proposed recently for hard convex bodres. IS employed for the dcscrlption of the P-V-T behdvlour of hard dumbbells Theoretical VAICS of the second and the third vuidl coefficients and the compressibdlty tactor agree well with the Monte Carlo data.
Equations of state of mixtures of hard dumbbells
โ Scribed by E. Enciso; J. Gil; S. Lago
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 267 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Two ways to predict pVT behavior of hard-dumbbell mixtures in the fluid region are proposed. These are adaptations of the hard convex body equation devised by Boubl~ and an extension of the first Barker:Henderson perturbation theory. Calculated compressibility factors show good agreement with the ideal mixing assumption and yield a useful equation of state.
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