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EPR study of Fe3+and Mn2+in CeO2and ThO2

✍ Scribed by J. Prohaska; M. Trömel; H. Rager

Book ID
113000910
Publisher
Springer Vienna
Year
1993
Tongue
English
Weight
512 KB
Volume
5
Category
Article
ISSN
0937-9347

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EPR study of osmium species derived from
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✍ V.A. Shvets; A.L. Tarasov; V.B. Kazansky; H. Knözinger 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 367 KB

High-valence osmium ions (OS'+ or 0s" ) were stabilized on CeOz and Th02, when the initially impregnated cluster OSCAR was decomposed under oxidizing conditions. This is in contrast to the formation of low-valence ions (OS'+ and 0~~') on Al,03. The presence of osmium on Ce02 and Th02 presumably modi