EPR study of bis-(N,N-diethylthioselenogarbamato)-copper(II)
β Scribed by J. Stach; R. Kirmse; E. Hoyer; S. Wartewig
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 286 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
The EPR spectrum of Cu(lI)-bis-(di-a-butyldiselenocarbamatc) was measured in solution. The Cu-HFS allows an estimate of the degree of covnlcncy for the Cu-Se o-bond. It was compared with parameters for some sulphur analogous complexes.
The EPR spectra of bis(3quinolinethiohto)copper(II) and bis(SquinoIinoIato)copper(II) complexes arc re'corded both at 300 K and 7'7 K. The EPR parameters are obtained and the coefficients of the MO of the unpaired e!ectron are calculated. It is shown mat replacing of 0 atam with S cause a more str