EPR Studies on the intermolecular interactions of bis(di-ethanol-dithiocarbamato) copper(II)
β Scribed by V. Iliev; N.D. Yordanov
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 256 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0167-7322
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## Abstract Polycrystalline samples of dithiophosphate (dtp) complexes Cu^II^[Cu(R~2~dtp)~2~], magnetically diluted in Ni (R~2~dtp)~2~, Pd(R~2~dtp)~2~ or Pt(R~2~dtp)~2~ matrices (R = CH~3~, C~2~H~5~ or __i__βC~3~H~7~) were studied. ENDOR transitions for the ^1^H and ^31^P nuclei belonging to the co
A single-crystal EPR sxdy of bis(O,O'di-iso-propyl-dithiophospharo) copper(U), [(~CJH,O)~PSSJICU, ma,onetically diluted in the corresponding Ni(I1) comples is repor!ed. The superhyperfine splitting from 31P nuclei of the l&ands is isotropic. The unpaired electron density on the dith.iophosphate liga