EPR studies of [O−·O2] complexes on MgO surface and their stabilization centers
✍ Scribed by Volodin, A. M.
- Book ID
- 112685381
- Publisher
- Springer
- Year
- 1991
- Tongue
- English
- Weight
- 240 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0133-1736
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Electron panmagnetic resonance studies of 1 ,e m 241Am doped barium slide powder llave been caried out 11 77 IL In freshly prepared samples a sextet with prominent ml dependent line widths (with g = 2.085 and A = 25 G) was observed besidesashsrpsextet with\_?=?\_01 1 and-4 = 10G\_Inadditionthespectm
We have investigated the interaction of O~-with Mg 2+ ions at terraces, edges and comers and with the Fs centers of the MgO (100) surface by means of ab initio cluster model wavefunctions. While O 2 is unbound or weakly bound at surface cations, O~-is electrostatically bound with adsorption energies