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Epr studies of copper(II) and oxovanadium(IV) dithiophosphate complexes in the solid state

✍ Scribed by N.D. Yordanov; D. Shopov


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
711 KB
Volume
19
Category
Article
ISSN
0022-2860

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A series of X-band electron paramagnetic resonance (EPR) spectra were obtained in the temperature range 120-280 K at 10 K intervals for the bis(acetylacetonate) complexes of copper(II) and oxovanadium(IV) cations in dimethylformamide. The magnetic parameters and molecular rotational correlation time

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A single-crystal EPR sxdy of bis(O,O'di-iso-propyl-dithiophospharo) copper(U), [(~CJH,O)~PSSJICU, ma,onetically diluted in the corresponding Ni(I1) comples is repor!ed. The superhyperfine splitting from 31P nuclei of the l&ands is isotropic. The unpaired electron density on the dith.iophosphate liga