EPR parameters and ionic-covalent transition in solids

✍ Scribed by E. Simanek; K.A. Mueller

• Publisher: Elsevier Science
• Year: 1970
• Tongue: English
• Weight: 283 KB
• Volume: 4
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(70)85021-7

✦ Synopsis

The anomalous change of EPR parameters of half-filled 3d ions in various compounds with the eovalency pnramctor is discussed in view of the recentiy proposed ionic-covalent transition. It is pointed out that the pnrmeters g, a and D are sensitive to the long-range interaction bringing up the transition, whereas A reflects the local otuster bonding properties.