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Covalency parameters in transition metal complexes from ESR and quadrupole resonance

✍ Scribed by B.B Garrett

Publisher
Elsevier Science
Year
1974
Weight
260 KB
Volume
14
Category
Article
ISSN
0022-2364

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Polar solvent structural parameters from protonation equilibria of aliphatic and alicyclic diamines and from absorption bands of mixed-valence transition-metal complexes
✍ A.A. Kornyshev; J. Ulstrup πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 671 KB

We have applied non-local electrostatic theory in combination with a simple solute model to obtain solvent structural properties in terms of the short-range dielectric constant, Z, and the correlation length for the solvent polarization fluctuations, A. These parameters are fitted to experimental da