EPR of Transient Free Radicals during Photochemical Reactions in High Temperature and Pressure Gases
โ Scribed by Batchelor, S. N.; Henningsen, B.; Fischer, H.
- Book ID
- 126996161
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 177 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The rotating-sector method has been applied to the photoinitiated radical-chain decomposition of formamide at 300ยฐC to measure the rate constant for the bimolecular disappearance of NH2 radicals. The decomposition is propagated by the reactions Conditions were chosen so that reaction (1) was rate c
The photolysis of formamide vapor at 2062 has been studied in a flow system with results essentially similar to those obtained previously under static conditions and higher conversions. The rotating-sector technique has been applied to the radical-chain decomposition of formamide under conditions (3
## Abstract The initiation of free radical chain reactions by singlet carbene biradicals is proposed for homogeneous oxidation of typical unsaturated hydrocarbons, including ethylene, allene, and propyne. The mechanism features the production of singlet vinylidene and methylvinylidene by 1,1โH~2~ e