EPR of Mn2+ in cobalt fluosilicate hexahydrate
β Scribed by Geetha Jayaram; G.Sivarama Sastry
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 310 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The EPR of Mn*+ in cobalt fluosihcate hexahydrate has been stu&ed at room temperature_ An axial spm-hamiltoman euplamed the observed spectrum. The presence of a single Mn** sate 111 an octahedral oxygen environment was confirmed A phase transition at -55Β°C was observed.
π SIMILAR VOLUMES
EPR of Mn 2Γ· has been studied in cobalt ammonium selenate hexahydrate from -~90 K to ~300 K and the spin-hamiltonian parameters determined. It has been found that replacement of S by Se does not cause much change in the strength and symmetry of the crystal field at the divalent cation site in Tutton