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EPR of axial adducts of cobalt(II) tetraphenylporphyrin

โœ Scribed by Abbas Pezeshk; Peter E. Davison; Frederick T. Greenaway

Book ID
103107945
Publisher
Elsevier Science
Year
1980
Weight
132 KB
Volume
16
Category
Article
ISSN
0020-1650

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Axial coordination of azaferrocene and d
Axial coordination of azaferrocene and dioxygen to cobalt(II) porphyrins. Photochemistry of six-coordinated adducts
โœ J. Zakrzewski; C. Giannotti ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 617 KB

The coordination of azaferrocene to cobalt(B) porphyrins (COP) and the photochemistry of the resulting five-and six-coordinated complexes were studied by electron spin resonance spectroscopy. The five-coordinated complexes COP(B) (B = azaferrocene) are photostable, whereas the six-coordinated comple