For the interpretation of the EPR lineshape of incommensurate phases there exist many theoretical models. We suppose a simple physical model to interpret the lineshape of the Mn 2+ EPR spectrum of the first incommensurate phase of betaine calcium chloride dihydrate (BCCD) and discuss it in compariso
EPR line shape of Mn2+ in BCCD single crystals in the incommensurate phase
β Scribed by R. Heidler; H. Metz; M. le Maire; G. Schaack; W. Windsch
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 441 KB
- Volume
- 209
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
A simple physical model is used to interpret the line shape of the Mn 2+ EPR spectrum of the first incommensurate phase of betaine calcium chloride dihydrate and it is discussed in comparison with other models. Furthermore, the critical behavior of BCCD at the normal to incommensurate phase transition on the basis of our model is investigated. The influence of the MnzC impurities on the phase sequence of BCCD is investigated by dielectric measurements.
π SIMILAR VOLUMES
Line widths of the EPR spectrum of V02+ . m NH4CI are found to show mIdependence, and obey Kivelson's formula for line-widths in liquids. Quantitative agreement with Kivelson's theory could not be obtained by using low temperature data. and the probable reasons are discussed. Recently Sastry and Ven