Epr characterization of alcohol complexes of ferric myoglobin and hemoglobin
β Scribed by Arthur S. Brill; Francis G. Flamingo; Don A. Hampton
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 513 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0162-0134
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π SIMILAR VOLUMES
Calcularions arc presenlcd for the EPR g vslues ot' fcrrtc iron in 3 cryst,d field with axial and rhombic symmetry components for rl spin state which is ZI qu.mtum mechanical mixture of intermediate-spin (S = j/2) and high-spin (S = S/2) componunts. The crystai field pnramcter /-i/G 1 is discussed i
The mechanism of the a&oxidation of ferrocytochrome c catalysed by some copper complexes has been established. In most cases the rate determining step was found to be the one electron oxidation of the cytochrome by the copper(H) species, which was followed by the rapid reoxidation of the resulting C