EPR Parameters of quantum mixed-spin ferric complexes with rhombic and tetragonal symmetry

✍ Scribed by Martin M. Maltempo; Mark E. Eberhart

• Publisher: Elsevier Science
• Year: 1984
• Tongue: English
• Weight: 417 KB
• Volume: 108
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(84)85721-8

✦ Synopsis

Calcularions arc presenlcd for the EPR g vslues ot' fcrrtc iron in 3 cryst,d field with axial and rhombic symmetry components for rl spin state which is ZI qu.mtum mechanical mixture of intermediate-spin (S = j/2) and high-spin (S = S/2) componunts. The crystai field pnramcter /-i/G 1 is discussed its tt more fundamenlal measure of rhombic distortion than the spin ii~~~iltoni~n ratio k-/O.