An approach joining highly diastereoselective Mukaiyama aldol reaction (process A) to the following radical debromination reaction (process B) provides a reliable way to the stereoselective divergent synthesis of polypropionate frameworks. A practical and reliable synthesis of the complete set of pr
Epoxyamide-Based Strategy for the Synthesis of Polypropionate-Type Frameworks
✍ Scribed by Sarabia, Francisco; Martín-Gálvez, Francisca; García-Castro, Miguel; Chammaa, Samy; Sánchez-Ruiz, Antonio; Tejón-Blanco, José F.
- Book ID
- 124063472
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 330 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0022-3263
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
A new strategy for convergent synthesis of trans-fused polyethers based on palladium(0)catalyzed Suzuki cross-coupling reaction of alkylboranes with cyclic enol triflates has been developed. The present method allows to construct polyether frameworks rapidly and efficiently.