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Epoxide synthesis in the butadiene-iron tricarbonyl series

โœ Scribed by J.P Lellouche; P Breton; J.P Beaucourt; L Toupet; R Gree

Book ID
104221314
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
244 KB
Volume
29
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The synthesis of functionalized epoxide-alcohols 8 to 11 is reported. The Sharpless procedure IJ'BHP-VO(acac)d is fully compatible with the presence of an organoiron complex.

๐Ÿ“œ SIMILAR VOLUMES

(2-Stannylated butadiene) tricarbonyl ir
(2-Stannylated butadiene) tricarbonyl iron complexes: Practical reagents for the synthesis of 2-acyldienes
โœ Pierre-Jean Colson; Michel Franck-Neumann; Madjid Sedrati ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 237 KB

A new route to the stable (2-acylbutadiene) tricarbonyl iron complexes is described, based on the palladium catalyzed coupling between acid chlorides and 2-stannylated butadiene complexes . Conjugated dienes bearing an electron-withdrawing group in position 2 are very reactive derivatives which are