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Epoxidation with molecular oxygen in the presence of PdCl (NO2) (CH3CN)2

✍ Scribed by Andreas Heumann; Frédéric Chauvet; Bernard Waegell

Book ID
104220952
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
121 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis

Several mono or non conlugated dlolefins are submitted to the action of oxygen in presence of catalytic amounts of Pdcl(No2) (cH~CN)~. Depending on the olefln structures methylketones or epoxides are obtained.

We report our preliminary results about the oxidation of mono and bicyclic oleflns') In presence of nltro palladium complex 1 (L=CH3CN)2). A redox process

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Epoxidation of methyl oleate with molecu
Epoxidation of methyl oleate with molecular oxygen in the presence of aldehydes
✍ Angela Köckritz; Michael Blumenstein; Andreas Martin 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 248 KB

## Abstract The epoxidation of methyl oleate with molecular oxygen in the presence of aldehydes was investigated and optimized. Epoxide yields up to 99% were observed in organic solvents. The preponderant radical reaction was started by a single organic radical chain initiator, without using a meta