Epoxidation of olefins with molecular oxygen in the presence of cobalt complexes
β Scribed by Budnik, Richard A.; Kochi, Jay K.
- Book ID
- 127191237
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 814 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-3263
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## Abstract The epoxidation of methyl oleate with molecular oxygen in the presence of aldehydes was investigated and optimized. Epoxide yields up to 99% were observed in organic solvents. The preponderant radical reaction was started by a single organic radical chain initiator, without using a meta
Several mono or non conlugated dlolefins are submitted to the action of oxygen in presence of catalytic amounts of Pdcl(No2) (cH~CN)~. Depending on the olefln structures methylketones or epoxides are obtained. We report our preliminary results about the oxidation of mono and bicyclic oleflns') In p