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Epoxidation of Various Functionalized Olefins by a Ti-MWW/H2O2 Catalytic System

✍ Scribed by Ningning LI; Yueming LIU; Haihong WU; Xiaohong LI; Wei XIE; Zhonglin ZHAO; Peng WU; Mingyuan HE

Publisher: Elsevier Science
Year: 2008
Weight: 296 KB
Volume: 29
Category: Article
ISSN: 1872-2067
DOI: 10.1016/s1872-2067(08)60018-2

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✦ Synopsis

The catalytic properties of Ti-MWW catalysts for the epoxidation of olefins with different functional groups using hydrogen peroxide as an oxidant were studied. Ti-MWW shows higher olefin conversion and epoxide selectivity than the conventional titanosilicate TS-1. Solvents influence the catalytic activity of Ti-MWW, and water is the best one in the epoxidation of ethyl acrylate and allyl acetate. The functional groups with high electrophilicity and adjacent to the C=C bonds retard the catalytic activity for olefin epoxidation.

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