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Catalytic Enantioselective Epoxidation of Unfunctionalized Olefins: Utility of a Ti(Oi—Pr)4—Salan—H2O2 System.

✍ Scribed by Kazuhiro Matsumoto; Yuji Sawada; Tsutomu Katsuki


Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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The catalytic properties of Ti-MWW catalysts for the epoxidation of olefins with different functional groups using hydrogen peroxide as an oxidant were studied. Ti-MWW shows higher olefin conversion and epoxide selectivity than the conventional titanosilicate TS-1. Solvents influence the catalytic a