Epitaxy of (poly(2,5-diheptyl-p-phenylene) on ordered polytetrafluoroethylene
β Scribed by Fahlman, M.; Rasmusson, J.; Kaeriyama, K.; Clark, D.T.; Beamson, G.; Salaneck, W.R.
- Book ID
- 123592424
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 469 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0379-6779
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## Abstract The synthesis of substituted poly(__p__βphenylenenvinylene) (PPV) was carried out via metathesis polycondensation of 2,5βdiheptylβ1,4βdivinylbenzene (DHepDVB). A stable molybdenumcarbene complex served as catalyst. The preparation of the educt employed (DHepDPV, 3a) is described. The ob
The thermal behavior of poly(para-2,5-didecyl-p-phenylene) has been investigated by differential scanning calorimetry and real time X-ray diffraction. Poly(para-2,5-didecyl-p-phenylene) is a semicrystalline material that crystallizes in a layered structure. The system exhibits two thermal transition