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Enzymes in organic synthesis. 2. Synthesis of enantiomerically pure prostaglandin intermediates by Enzymatic Hydrolysis of (1SR, 5RS, 6RS, 7RS)-7-acetoxy-6-acetoxymethyl-2-oxabicyclo[3.3.0]octan-3-one

✍ Scribed by Dr. Fritz Theil; Prof. Dr. Sc. Nat. Hans Schick; Dr. Peter Nedkov; Dr. Monika Böhme; Dr. Barbara Häfner; Prof. Dr. Sc. Nat. Sigfrid Schwarz

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
400 KB
Volume
330
Category
Article
ISSN
1615-4150

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## Abstract Lipase Amano PS is a suitable biocatalyst for the highly regio‐ and enantioselective transesterification of the racemic prostaglandin building block (1__S__~\*~,5__R__\*,6__R__\*,7__R__\*)‐(±)‐7‐hydroxy‐6‐hydroxymethyl‐2‐oxabicyclo[3.3.0]octan‐3‐one (__rac__‐1) yielding (1__S__,5__R__,6