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Crystal and molecular structure of (1SR, 5RS, 6SR, 7SR)-7-chlor-6-hydroxy-2-oxabicyclo[3.3.0]octan-3-one

✍ Scribed by M. Ramm; B. Schulz; Dr. R. Mahrwald

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
185 KB
Volume
24
Category
Article
ISSN
0232-1300

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✦ Synopsis

Short Notes M. RAMM, B. SCHULZ, R. MAHRWALD Zentralinstitut fur physikalischo Chemie der Akadcmie dcr Wisscnschaften der DDR, Berlin, and Zentralinstitut fur organische Chcmie der Akadcmie dcr Wisscnschaften der DDR, Berlin Crystal and Molecular Structure of (lSR, 5RS, 6SR, 7SR)-7 -Chlor -6 -hydroxy -2 -0xabicyc10 [ 3.3 .O] oct an-3 -one

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chains of Sr 9/8 TiS 3 and Sr 8/7 TiS 3 contain oligomer units (Oh) n (n ‫؍‬ 4, 5) made up of face-sharing TiS 6 octahedra (Oh). Given the (TiS 3 ) chains aligned along the z direction, the only occupied d-block levels of each (TiS 3 ) chain are the most sigma bonding level of each (Oh) n oligomer,