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Enzymes in organic syntheses. 19. Evaluation of the stereoselectivities of horse liver alcohol dehydrogenase; catalyzed oxidoreductions of hydroxy- and ketothiolanes, -thianes, and -thiepanes

โœ Scribed by Jones, J. Bryan; Schwartz, Harold M.


Book ID
127176923
Publisher
NRC Research Press
Year
1981
Tongue
French
Weight
346 KB
Volume
59
Category
Article
ISSN
0008-4042

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Stereoselectivity of horse liver alcohol
โœ Yoshimitsu Yamazaki; Kuniaki Hosono ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 141 KB

1,2\_Bis(hydroxymethyl)ferrocene was oxidized by horse liver alcohol dehydrogenase preferentially to (lR, 2S)-(hydroxymethyl)aldehyd, while 1,2\_diformylferrocene was reduced to the (12, 2!)-antipode, The usefulness of enzymes as catalysts for asymmetric synthesis has been widely recognized. 1 Howe