𝔖 Bobbio Scriptorium
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Enzymatic aldol reaction/isomerization as a route to unusual sugars

✍ Scribed by J.Robert Durrwachter; H.M. Sweers; K. Nozaki; Chi-Huey Wong


Book ID
104218316
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
231 KB
Volume
27
Category
Article
ISSN
0040-4039

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## Abstract The treatment of the α‐oxoketene dithioacetal sugar derivatives 2 and 7 with concentrated hydrochloric acid in THF leads to the open‐chain uloses 3 and 8. The reaction mechanism can be rationalized as a retro‐aldol reaction. This rationalization was supported by reacting 2 and 7 with DC