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Enzymatic activity catalysing exo-selective Diels?Alder reaction in solanapyrone biosynthesis

✍ Scribed by Oikawa, Hideaki; Katayama, Kinya; Suzuki, Yuichi; Ichihara, Akitami


Book ID
125849694
Publisher
The Royal Society of Chemistry
Year
1995
Tongue
English
Weight
324 KB
Volume
13
Category
Article
ISSN
0022-4936

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Diels-Alder reacfions ofsilyloxydiene 1 derivedfrom 1 -acetylcyclohexene with imincs 26 and 2c occur with high exe selectivity depending upon experimental cundirinns: exo cycloadducts 3h-c are e\_zciusively formed under kinetic control using rerf-butyIdimethyt.rilyllriflate us catalyst. In [he prese