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Entropic and conformational study of isolated double-tethered chains by three-dimensional lattice simulations

✍ Scribed by Kazuhito Shida; Atsuo Kasuya; Yoshiyuki Kawazoe


Book ID
103882744
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
190 KB
Volume
382
Category
Article
ISSN
0378-4371

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✦ Synopsis


Double-tethered polymers are a kind of linear polymer with a peculiar topological constraint; that is, both of its endpoints are attached to a plane which the polymer segments cannot penetrate. The effects of the constraint on the polymer's configurational and entropic properties were investigated by means of a three-dimensional lattice simulation that combined a previously proposed idea with a very efficient chain generation algorithm. In particular, the value of a topology-dependent critical exponent was estimated for the double-tethered configurations. This data is the first report on isolated and double-tethered chains. Also, two optional types of tethered-polymer were investigated as asymptotes of the double-and single-tethered configurations.


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