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Enthalpy–Entropy Compensation for Micellization and Other Hydrophobic Interactions in Aqueous Solutions

✍ Scribed by Jolicoeur, Carmel; Philip, Patrick R.


Book ID
120345985
Publisher
NRC Research Press
Year
1974
Tongue
French
Weight
287 KB
Volume
52
Category
Article
ISSN
0008-4042

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Enthalpy–Entropy Compensation Phenomenon
✍ Gohsuke Sugihara; Mihoko Hisatomi 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 81 KB

Based on previously reported thermodynamic data such as changes of the Gibbs energy (⌬G°m), the enthalpy (⌬H °m), and the entropy (⌬S°m) on micelle formation of more than 15 species of surfactants (including nonionic, anionic, and cationic surfactants), plots of ⌬H °m vs ⌬S°m (not of ⌬S°m vs ⌬H °m,