Enthalpy–Entropy Compensation Phenomenon
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Gohsuke Sugihara; Mihoko Hisatomi
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Article
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1999
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Elsevier Science
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English
⚖ 81 KB
Based on previously reported thermodynamic data such as changes of the Gibbs energy (⌬G°m), the enthalpy (⌬H °m), and the entropy (⌬S°m) on micelle formation of more than 15 species of surfactants (including nonionic, anionic, and cationic surfactants), plots of ⌬H °m vs ⌬S°m (not of ⌬S°m vs ⌬H °m,