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Enthalpy of formation, ΔH°fNO3−(g) and solvation, δH°solvNO3−(g) of the gaseous nitrate ion Charge distribution in the No3− ion and lattice energies of LiNO3, NaNO3 and KNO3

✍ Scribed by H.D.B Jenkins; T.C Waddington


Book ID
118909044
Publisher
Elsevier Science
Year
1972
Weight
348 KB
Volume
34
Category
Article
ISSN
0022-1902

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The gaseous azide ion, N3−: Enthalpy of
✍ H.P. Dixon; H.D.B. Jenkins; T.C. Waddington 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 517 KB

The calculations reported here atign a charge qN = -0.52 eIectron units to the terminal nitrogen atoms in the azide ion and a value of 141.9 M mole4 to the enthaipy of formation of thejaseous azide ion, A@fl&)).fhe, total Iattia? potential energies\_? found to be: EpotfNaN3) = 725.1 kJ mole and E&Rb

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The same chemiluminescent spectrum of HNO was obtained in both the reaction systems of 0(3P) + CaHe + NO + 02 (\* A,)/02 and H + NO + 02( 'Ag)/Oa. The reaction mechanism for producing the excited HNO is proposed to be -HNO('A') + 02 ( 'Ag) + HNO(3A", + 0s (3X,) , HNOc3A") + 02 ('A,) --t HNO('A") +