The standard (p°= 0.1 MPa) enthalpies of combustion at the temperature T = 298.15 K were measured by static-bomb calorimetry for crystalline 4-nitropyridine N-oxide and for pyridine-3-carboxylic acid N-oxide. The standard enthalpies of sublimation at T = 298.15 K were measured for 4-nitropyridine N-
Enthalpies of combustion of the pyridine N-oxide derivatives: 4-methyl-, 3-cyano-, 4-cyano-, 3-hydroxy-, 2-carboxy-, 4-carboxy-, and 3-methyl-4-nitro, and of the pyridine derivatives: 2-carboxy-, and 4-carboxy-. The dissociation enthalpies of the N-O bonds
✍ Scribed by Maria D.M.C. Ribeiro da Silva; M. Agostinha; R. Matos; M.Cláudia Vaz; Luı́s M.N.B.F. Santos; G. Pilcher; W.E. Acree Jr.; Joyce R. Powell
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 155 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0021-9614
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✦ Synopsis
The standard pЊ s 0.1 MPa molar enthalpies of formation ⌬ H cr at T s 298.15 K were 2 4-CO HPyNO y381.2 " 1.3 136.1 " 1.2 259.5 " 5.0 2 3-Me4NO PyNO y19.5 " 3.4 106.7 " 2.0 263.4 " 7.1 2 2-CO HPy y341.0 " 1.2 98.0 " 2.3 2 4-CO HPy y348.7 " 1.6 113.9 " 4.4 2 T Ž . Comparison has been made with D N-O values in pyridine N-oxide derivatives. ᮊ 1998 m Academic Press
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