𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Enthalpies of combustion of 2-iodosobenzoic acid and 4-nitrosophenol: the dissociation enthalpy of the I–O bond

✍ Scribed by M.D.M.C Ribeiro da Silva; M.A.R Matos; M.L.C.C.H Ferrão; L.M.P.F Amaral; M.S Miranda; W.E Acree Jr; G Pilcher

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
119 KB
Volume
31
Category
Article
ISSN
0021-9614

No coin nor oath required. For personal study only.

✦ Synopsis

The standard ( p o = 0.1 MPa) molar enthalpies of combustion in oxygen, at T = 298.15 K, for crystalline 2-iodosobenzoic acid, (OI)C 6 H 4 COOH, and 4-nitrosophenol, (ON)C 6 H 4 OH, were measured by rotating-bomb calorimetry and static-bomb calorimetry, respectively. These values were used to derive the standard molar enthalpies of formation of the crystalline compounds.

An indirect method was used for assessing the dissociation enthalpy of the (I-O) bond in the iodoso derivative, D o m (I-O)/(kJ • mol -1 ) = (264.5 ± 8.1), which is the first value reported for an iodine-oxygen bond in an organic molecule.

📜 SIMILAR VOLUMES

Enthalpies of combustion of 4-nitropyrid
Enthalpies of combustion of 4-nitropyridineN-oxide and pyridine-3-carboxylic acidN-oxide: the dissociation enthalpies of the N—O bonds in pyridineN-oxide derivatives
✍ W.E. Acree Jr.; Sheryl A. Tucker; Maria D.M.C. Ribeiro da Silva; M. Agostinha R. 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 369 KB

The standard (p°= 0.1 MPa) enthalpies of combustion at the temperature T = 298.15 K were measured by static-bomb calorimetry for crystalline 4-nitropyridine N-oxide and for pyridine-3-carboxylic acid N-oxide. The standard enthalpies of sublimation at T = 298.15 K were measured for 4-nitropyridine N-

The Dissociation Enthalpies of Terminal
The Dissociation Enthalpies of Terminal (N—O) Bonds in Organic Compounds
✍ William E. Jr. Acree; Geoffrey Pilcher; Maria D. M. C. Ribeiro da Silva 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 8 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.