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Enthalpies of combustion, formation, and vaporization of spiro[4.5]decane, spiro[5.5]undecane, and 7-n-hexadecylspiro[4.5]decane

โœ Scribed by Subach, Daniel J.; Zwolinski, Bruno J.


Book ID
126837929
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
494 KB
Volume
20
Category
Article
ISSN
0021-9568

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Synthesis and Characterization of Optically Active Spiro[4.5]decanes. -Three different dienes (I), substituted with a chiral auxiliary at the 1-position, and dienophiles (II) or (VII) undergo a Diels-Alder cycloaddition with quite good diastereofacial selectivity. The Si-exo and Re-endo diastereomer