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Entanglement Networks of 1,2-Polybutadiene Cross-Linked in States of Strain. 8. Trapping of Entanglements in Relaxed and Unrelaxed Configurations

✍ Scribed by Kan, Hsin-Chia; Ferry, John D.

Book ID
126129960
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
596 KB
Volume
12
Category
Article
ISSN
0024-9297

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Entanglement networks of 1,2-polybutadie
Entanglement networks of 1,2-polybutadiene crosslinked in states of strain. IV. States of ease and stress–strain behavior
✍ Rick L. Carpenter; Ole Kramer; John D. Ferry πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 446 KB πŸ‘ 1 views

Linear 1,2-polybutadiene, glass transition temperature (T,) -18OC, is crosslinked a t -10' to -2OOC by y irradiation while strained in simple extension, with extension ratios (&) from 1.2 to 2.7. After release, the sample retracts to a state of ease (A,) a t room temperature. From equilibrium stress