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Entanglement Networks of 1,2-Polybutadiene Cross-Linked in States of Strain. 3. Effect of Temperature

✍ Scribed by Carpenter, Rick L.; Kramer, Ole; Ferry, John D.


Book ID
120057206
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
390 KB
Volume
10
Category
Article
ISSN
0024-9297

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Entanglement networks of 1,2-polybutadie
✍ Rick L. Carpenter; Ole Kramer; John D. Ferry πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 446 KB πŸ‘ 1 views

Linear 1,2-polybutadiene, glass transition temperature (T,) -18OC, is crosslinked a t -10' to -2OOC by y irradiation while strained in simple extension, with extension ratios (&) from 1.2 to 2.7. After release, the sample retracts to a state of ease (A,) a t room temperature. From equilibrium stress