Enones with strained double bonds. 4. Bicyclo[5.3.1]undecane system
โ Scribed by House, Herbert O.; Sieloff, Ronald F.; Lee, Thomas V.; DeTar, Marvin B.
- Book ID
- 126422664
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 948 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
The Cyclopropylalkylidenecyclopropane Thermal Double Ring Expansion. A Novel Route to the Bicyclo[5.3.1]undecane Skeleton of the AB Ring System of Taxanes. -The mechanism of the reaction is explained by the initial formation of a diradical followed by opening to a homoallylic biradical which closes
## Abstract The synthesis of a ^11^Cโlabelled methyl stannane, (5โ[^11^C]methylโ1โazaโ5โstannaโbicyclo[3.3.3]undecane (**2**)), and its use in palladiumโmediated Stille reactions to form [^11^C]CโC bonds are described. Stannane **2** was synthesized from iodo[^11^C]methane, 5โchloroโ1โazaโ5โstannaโ