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Enolization of ketones. IV. Rate and orientation of base-catalyzed deuteration of some methyl ketones

✍ Scribed by Rappe, Christoffer; Sachs, William H.

Book ID
127140530
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
328 KB
Volume
32
Category
Article
ISSN
0022-3263

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## Abstract A synthesis and a base‐catalyzed exchange reaction was developed under mild conditions to deuterate and subsequently tritiate the methyl group of the base sensitive diketone 1‐biphenyl‐4‐ylpropane‐l,2‐dione depicted in Figure 1. Using Et~3~N as base, deuterium incorporation of the methy