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Enolization and Hydrolysis of 7-Nitroisochroman-3-one in Aqueous Solution: Generation of a Relatively Stable Lactone Enolate

✍ Scribed by Hawkinson, David C.; Feiock, Jeffrey M.; Nevy, John B.; Wu, Yue-Zhong


Book ID
127315541
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
148 KB
Volume
63
Category
Article
ISSN
0022-3263

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Flash photolysis of 4-diazoisochroman-3-
✍ Y. Chiang; S. J. Eustace; E. A. Jefferson; A. J. Kresge; V. V. Popik; R.-Q. Xie πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 104 KB πŸ‘ 2 views

Flash photolysis of 4-diazoisochroman-3-one in aqueous solution resulted in loss of nitrogen and transient production of the a-carbonylcarbene 3-ketoisochroman-4-ylidene, the hydration of which generated a shortlived species that was identified as the enol isomer of the lactone, 4-hydroxyisochroman-