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Flash Photolytic Investigation of 4-Diazoisothiochroman-3-one in Aqueous Solution: Observation of a Short-Lived Carboxylic Acid Enol

โœ Scribed by Chiang, Y.; Jefferson, E. A.; Kresge, A. J.; Popik, V. V.


Book ID
125969121
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
140 KB
Volume
121
Category
Article
ISSN
0002-7863

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Flash photolysis of 4-diazoisochroman-3-
โœ Y. Chiang; S. J. Eustace; E. A. Jefferson; A. J. Kresge; V. V. Popik; R.-Q. Xie ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 104 KB ๐Ÿ‘ 2 views

Flash photolysis of 4-diazoisochroman-3-one in aqueous solution resulted in loss of nitrogen and transient production of the a-carbonylcarbene 3-ketoisochroman-4-ylidene, the hydration of which generated a shortlived species that was identified as the enol isomer of the lactone, 4-hydroxyisochroman-